It probably comes down in some respects to the beauty of the word. It just looks strong. HEROINE. If you avoid thinking about the drug name contained within it, it's a pretty interesting assemblage of letters, with the O anchoring it all.
Maybe the "-ess" is problematic. What I like about heroine is that it's not as obviously derivative of hero (even though it is derivative, in point of fact). The "-ine" is less frequently used, and it shifts the word's pronuncitation, to make it a new thing. A heroine has free will. She isn't just a suffixed word. She has her own (vowel) sound.
I'm on a bus with no wifi other than on my phone, so I can't look up research on this that would bolster my flimsy argument, but I like thinking about this. If anyone knows of any citations that might be helpful, please send them my way!
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